In addition to catalytic initiation of radicals, the review discusses alkyl generation using non-equilibrium plasma. Gold supported on sulfated ceria-zirconia catalyst (Au-SCZ) is concluded to be a promising catalyst for further study. Comparison with other catalyst systems such as Li/Y 2O 3, Au/La 2O 3, Au-SCZ, BiOCl, B 2O 3/Al 2O 3, Co-N/Al 2O 3 and Pt/Al 2O 3 monoliths is included. ![]() The review focuses on the catalytic generation of alkyl radicals at moderate temperatures (550–650 ☌) using the Li/MgO system. Catalytic oxidative cracking is a combination of heterogeneous and homogeneous reactions the reaction is initiated on the catalyst surface followed by thermal gas phase cracking. ![]() A review on the catalytic oxidative cracking of light alkanes to alkenes is presented as an alternative route to steam cracking for production of alkenes.
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